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DOE-HDBK-1092-98
2. Dust accumulations are normally insufficient to interfere with the normal operation of
electrical equipment or other apparatus, but where combustible dust may be suspended in the
air as a result of infrequent malfunctioning of handling or processing equipment; and
3. Combustible dust accumulations on, in, or in the vicinity of the electrical equipment may be
sufficient to interfere with the safe dissipation of heat from electrical equipment or may be
ignitable by abnormal operation or failure of electrical equipment. (See Table 5-6.)
5.3.3 GROUPS
Until publication of the 1937 edition of the NEC, Class I hazardous locations were not subdivided;
a flammable gas or vapor was classified as presenting a single degree of hazard. It was recognized,
however, that the degrees of hazard varied with the substance and that equipment suitable for use
where gasoline was handled was not necessarily suitable for use where hydrogen or acetylene was
handled.
The difficulty of manufacturing equipment and enclosures for use in hydrogen atmospheres was also
recognized, as was the expense of the equipment. It was not logical from an engineering standpoint,
for example, to require in gasoline stations use of explosion-proof equipment that was also suitable
for use in hydrogen atmospheres. Not only would this unnecessarily increase the cost of the electrical
installation in one of the most common types of hazardous locations, but it would also make some
types of equipment unavailable. Even today, there are no listed motors or generators suitable for use
in Group A or B atmospheres. (See NEC Section 500-3 for more information on groups).
5.3.4 IGNITION TEMPERATURE
Ignition temperature of a substance, whether solid, liquid, or gaseous, is the minimum temperature
required to initiate or cause self-sustained combustion independently of the heating or heated
element.
Ignition temperatures observed under one set of conditions may be changed substantially by a change
of conditions. For this reason, ignition temperatures should be viewed only as approximations:
Ignition temperatures under one set of conditions may be changed substantially by a change of
conditions. Some of the variables known to affect ignition temperatures are percentage composition
of the vapor or gas-air mixture; shape and size of the space where the ignition occurs; rate and
duration of heating; kind and temperature of the ignition source, catalytic or other effect of materials
that may be present; and oxygen concentration. Another variable is the many differences in methods
and conditions of testing ignition temperature (size and shape of containers, method of heating, and
ignition source).
5.3.5 FLAMMABLE (EXPLOSION) LIMITS
As mentioned in Section 5.3.1.1, in the case of gases or vapors that form flammable mixtures with
oxygen, there is a minimum concentration of gas or vapor in air or oxygen below which propagation
of flame cannot occur on contact with a source of ignition. There is also a maximum concentration
of vapor or gas in air above which propagation of flame cannot occur. These boundary-line mixtures
5-24


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