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DOE-STD-1176-2004
c.
Define the following mass transfer terms and vapor-liquid equilibrium laws:
Absorption
Adsorption
Partition Coefficient
Raoult's Law
Dalton's Law
Henry's Law
Azeotropes
Phase Diagrams
Vapor-liquid Equilibrium
Binary Phase Equilibria
Multi-component Vapor Equlibria
Bubble-point, dew point, relative volatility
d.
Discuss how the vapor-liquid equilibrium laws may be applied to determine a
Composite Lower Flammability Limit in a vessel vapor space.
e.
Perform an example calculation demonstrating the use of mass transfer
coefficients to estimate a liquid to vapor mass transfer.
3.
Chemical processing personnel shall demonstrate an expert level knowledge of
stoichiometry and reaction kinetics.
Supporting Knowledge and/or Skills
a.
Balance a chemical reaction equation, and discuss the concepts of limiting
reactant and theoretical product yield.
b.
Discuss how a rate constant for a first order reaction may be determined from
experimental data.
c.
Discuss the effects of temperature, catalysts, agitation and other conditions upon
a reaction rate.
4.
Chemical processing personnel shall demonstrate an expert level knowledge of
process safety.
Supporting Knowledge and/or Skills
a.
Discuss key requirements of the Process Safety Management (PSM) Rule (29
CFR 1910.119).
b.
Discuss the role of Chemical Processing personnel in performing Process
Hazard Analysis and other parts of PSM.
c.
Discuss the following attributes of a Personnel Protection Program:
Material Safety Data Sheets (MSDS) and 29 CFR 1910.1200
Personal Protective Equipment
7


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