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DOE-HDBK-1100-2004
combustible;
NH3
toxic vapor;
anhydrous
cryogenic
ammonia
liquid spill
explosive
oxidizer;
Cl2
NCl3 formed
toxic vapor;
chlorine
with excess
cryogenic
chlorine or
liquid spill
heat
heat
heat
strong acid;
HF
generation,
generation,
corrosive;
anhydrous
liberating
liberating
toxic vapor
toxic vapors
toxic vapors
and liquid
fluoride
fire,
heat
heat
flammable;
C4H6
toxic gas
generation,
generation,
peroxidizes;
1,3-
generation
violent
violent
polymerizes;
butadiene
polymeriza-
polymeriza-
decomposes
tion
tion
none
material of
none
iron/chlorine
Fe, etc.
predicted
blistering
construction
predicted
fire if above
carbon steel
250ΕC (or
between
steel
100ΕC with
laminations
none
antioxidant
none
heat
heat
elevated
H2O
predicted
consumed,
predicted
generation,
generation,
pressure,
150# steam
leading to
liberating
liberating
temperature
polymeriza-
toxic vapors
toxic vapors
tion
combined NH3
Cl2
HF
C4H6
Fe, etc.
H2O
with... anhydrous
chlorine
anhydrous
1,3-
carbon steel
150# steam
ammonia
butadiene
fluoride
NOTE: Descriptions along diagonal are properties of materials by themselves.
All potential material interactions should be examined for incompatibilities. Even if process materials are relatively
non-hazardous when considered independently, some potentially dangerous interactions may occur when materials
are combined. Interactions between process chemicals, containment materials, and other materials with which the
chemicals come in contact can be examined in pairs by using an interaction matrix.
Figure 3.2 Example Interaction Matrix for Identifying Process Hazards
15


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