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 |  DOE-HDBK-1100-2004 combustible; NH3 toxic vapor; anhydrous cryogenic ammonia liquid spill explosive oxidizer; Cl2 NCl3 formed toxic vapor; chlorine with excess cryogenic chlorine or liquid spill heat heat heat strong acid; HF generation, generation, corrosive; anhydrous liberating liberating toxic vapor toxic vapors toxic vapors and liquid fluoride fire, heat heat flammable; C4H6 toxic gas generation, generation, peroxidizes; 1,3- generation violent violent polymerizes; butadiene polymeriza- polymeriza- decomposes tion tion none material of none iron/chlorine Fe, etc. predicted blistering construction predicted fire if above carbon steel 250ΕC (or between steel 100ΕC with laminations none antioxidant none heat heat elevated H2O predicted consumed, predicted generation, generation, pressure, 150# steam leading to liberating liberating temperature polymeriza- toxic vapors toxic vapors tion combined NH3 Cl2 HF C4H6 Fe, etc. H2O with... anhydrous chlorine anhydrous 1,3- carbon steel 150# steam ammonia butadiene fluoride NOTE: Descriptions along diagonal are properties of materials by themselves. All potential material interactions should be examined for incompatibilities. Even if process materials are relatively non-hazardous when considered independently, some potentially dangerous interactions may occur when materials are combined. Interactions between process chemicals, containment materials, and other materials with which the chemicals come in contact can be examined in pairs by using an interaction matrix. Figure 3.2 Example Interaction Matrix for Identifying Process Hazards 15 | 
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